What the?! How did we miss this one before??

The usually prim Anne Hathaway took her simple signature style and gave it a rock 'n roll edge at the MTV Movie Awards. The pumps and perfect curls kept it "Anne" while the leather gave it a funky, experimental twist. She has really been stepping out of the box lately and we are diggin' it.

And OMG! You guys! Are you loving this leather Sophia Kokosalaki piece as much as we are? Miss Sophia is certainly our designer d'jour!

• Sophia Kokosalaki dress, Yoox.com, $525